89000-82-8

Upstream product

• 865-36-1 thioformaldehyde 
• 120693-82-5 3,5-Di-O-benzyl-α-D-xylofuranose 
• 16054-77-6 3,5-di-O-benzyl-D-xylofuranose 
• 6160-65-2 1,1'-Thiocarbonyldiimidazole 
• 463-71-8 thiophosgene 
• 100-39-0 benzyl bromide 
• 41341-99-5 3,5-di-O-benzyl-1,2-O-isopropylidene-α-D-xylofuranose 
• 20031-21-4 1,2-O-isopropylidene-α-D-xylose 

Downstream Products

• 89063-83-2 propyl 3,5-di-O-benzyl-β-D-xylofuranose 
• 34382-30-4 propyl 3,5-di-O-benzyl-α-D-xylofuranose 
• 89000-85-1 (2R,3R,4R,5R)-4-Benzyloxy-5-benzyloxymethyl-2-(3-phenyl-propoxy)-tetrahydro-furan-3-ol 
• 89000-89-5 (2S,3R,4R,5R)-4-Benzyloxy-5-benzyloxymethyl-2-(3-phenyl-propoxy)-tetrahydro-furan-3-ol 
• 110237-88-2 1,4-anhydro-3,5-di-O-benzyl-2-deoxy-D-threo-pent-1-enitol 
• 126797-45-3 (3aR,5R,6S,6aR)-6-Benzyloxy-5-benzyloxymethyl-tetrahydro-1,4-dioxa-3-thia-pentalen-2-one 
• 89000-83-9 isopropyl 3,5-di-O-benzyl-β-D-xylofuranose 
• 89000-87-3 isopropyl 3,5-di-O-benzyl-α-D-xylofuranose 
• 89000-86-2 (2R,3R,4R,5R)-4-Benzyloxy-5-benzyloxymethyl-2-cyclohexyloxy-tetrahydro-furan-3-ol 
• 89000-90-8 (2S,3R,4R,5R)-4-Benzyloxy-5-benzyloxymethyl-2-cyclohexyloxy-tetrahydro-furan-3-ol 
• 581795-72-4 C₂₇H₂₉N₃O₈S 

Relevant academic research and scientific papers

Furanosyl Oxocarbenium Ion Conformational Energy Landscape Maps as a Tool to Study the Glycosylation Stereoselectivity of 2-Azidofuranoses, 2-Fluorofuranoses and Methyl Furanosyl Uronates

The 3D shape of glycosyl oxocarbenium ions determines their stability and reactivity and the stereochemical course of SN1 reactions taking place on these reactive intermediates is dictated by the conformation of these species. The nature and co

Synthesis of furanose glycals from furanose 1,2-diols and their cyclic thiocarbonate esters

Two new methods for the synthesis of furanoid glycals are described. Both procedures were shown to be faster and cheaper that those previously reported. Protected 1,2-dihydroxypento- and hexo-furanose derivatives with the D-xylo, D-gluco and D-ribo, D-all

The Synthesis and Reactivity of Cyclic Thiocarbonates Derived from Some Carbohydrate 1,2-Diols

The attempted synthesis of several carbohydrate 1,2-diols is reported, together with the transformation of two of these diols into cyclic thiocarbonates, namely 4,6-O-benzylidene-3-O-methyl-1,2-O-thiocarbonyl-α-D-glucose and 3,4-O-isopropylidene-1,2-O-thiocarbonyl-β-D-arabinose.The treatment of these thiocarbonates, and a furanose 1,2-thiocarbonate previously prepared by Mukaiyama, with methyl halides and with tributyltin hydride is discussed.A single-crystal X-ray diffraction study of 3,4-O-isopropylidene-1,2-O)-thiocarbonyl-β-D-arabinose is recorded.

A NEW METHOD FOR THE STEREOSELECTIVE SYNTHESIS OF β-XYLOFURANOSIDE

β-Xylofuranosides are stereoselectively synthesized in good yields by the successive treatment of the thiocarbonate, derived from 3,5-di-O-benzyl-D-xylofuranose, with methyl fluorosulfonate and hydroxy compounds in the presence of cesium fluoride.