89006-38-2Relevant academic research and scientific papers
Titanocene-catalyzed double silylation of dienes and aryl alkenes with chlorosilanes
Terao, Jun,Kambe, Nobuaki,Sonoda, Noboru
, p. 9697 - 9698 (2007/10/03)
Double silylation of 1,3-butadienes with chlorosilanes was found to proceed by using titanocene dichloride as the catalyst in the presence of (n)BuMgCl, giving rise to 1,4-disilylated 2-butenes in good yields. Aryl substituted alkenes also afforded 1,2-di
Generation of Metal-Free Silyl Anions from Disilanes and Fluoride Catalyst. Synthetic Reactions with Aldehydes and 1,3-Dienes
Hiyama, Tamejiro,Obayashi, Michio,Mori, Ichiro,Nozaki, Hitosi
, p. 912 - 914 (2007/10/02)
The Si-Si bond of disilanes is found to be cleaved by tetrabutylammonium fluoride (TBAF) in hexamethylphosphoric triamide to produce metal-free silylanion and triorganosilyl fluoride.The disilane/TBAF reagent was studied spectrometrically.Sythetic application of the reagent with a catalytic amount of TBAF is illustrated by the reaction with aldehydes and 1,3-dienes.
