890122-52-8

Upstream product

• 890122-51-7 N-(8-bromo-4-methoxy-2,5-dioxo-2,3,3a,4,5,8b-hexahydro-1H-4,8a-diaza-as-indacen-3-yl)-4-methyl-benzenesulfonamide 
• 624-83-9 methyl isocyanate 
• 890122-46-0 (3aR,8bS)-8-Bromo-4-methoxy-1,3a,4,8b-tetrahydro-4,8a-diaza-as-indacen-5-one 
• 890122-44-8 5-bromo-1-(4-tert-butoxycarbonyloxy-cyclopent-2-enyl)-1H-pyrrole-2-carboxylic acid methyl ester 
• 890122-54-0 5-bromo-1-(4-tert-butoxycarbonyloxy-cyclopent-2-enyl)-1H-pyrrole-2-carboxylic acid 
• 890122-45-9 Carbonic acid (1R,4S)-4-(2-bromo-5-methoxycarbamoyl-pyrrol-1-yl)-cyclopent-2-enyl ester tert-butyl ester 
• 890122-49-3 1-bromo-5-methoxy-6-(toluene-4-sulfonyl)-5a,5b,6,6a,7,7a-hexahydro-5H-5,6,7b-triaza-cyclopropa[b]-as-indacen-4-one 
• 890122-50-6 N-(8-bromo-2-hydroxy-4-methoxy-5-oxo-2,3,3a,4,5,8b-hexahydro-1H-4,8a-diaza-as-indacen-3-yl)-4-methyl-benzenesulfonamide 

Relevant academic research and scientific papers

A stereodivergent strategy to both product enantiomers from the same enantiomer of a stereoinducing catalyst: agelastatin

In this article, we report a full account of our recent development of pyrroles and N-alkoxyamides as new classes of nucleophiles for palladiumcatalyzed AAA reactions, along with application of these methodologies in the total synthesis of agelastatin A,

New class of nucleophiles for palladium-catalyzed asymmetric allylic alkylation. Total synthesis of agelastatin A

New classes of nucleophiles, pyrroles, and N-methoxyamides were developed for Pd-catalyzed AAA reactions. By varying the functional groups at the 2-position of pyrroles, either regioisomer of the piperazinone is available. Using one regioisomer, the total