890122-49-3

Upstream product

• 890122-46-0 (3aR,8bS)-8-Bromo-4-methoxy-1,3a,4,8b-tetrahydro-4,8a-diaza-as-indacen-5-one 
• 55962-05-5 [N-(p-tolylsulfonyl)imino]phenyliodinane 
• 890122-45-9 Carbonic acid (1R,4S)-4-(2-bromo-5-methoxycarbamoyl-pyrrol-1-yl)-cyclopent-2-enyl ester tert-butyl ester 
• 890122-54-0 5-bromo-1-(4-tert-butoxycarbonyloxy-cyclopent-2-enyl)-1H-pyrrole-2-carboxylic acid 
• 890122-44-8 5-bromo-1-(4-tert-butoxycarbonyloxy-cyclopent-2-enyl)-1H-pyrrole-2-carboxylic acid methyl ester 
• 55962-05-5 4-methyl-N-[(E)-phenyl-λ³-iodanylidene]benzenesulfonamide 

Downstream Products

• 890122-52-8 (5aS,5bR,8aR,9aS)-1-Bromo-8a-hydroxy-5-methoxy-8-methyl-6-(toluene-4-sulfonyl)-5,5a,5b,6,8,8a,9,9a-octahydro-5,6,8,9b-tetraaza-cyclopenta[b]-as-indacene-4,7-dione 
• 890122-51-7 N-(8-bromo-4-methoxy-2,5-dioxo-2,3,3a,4,5,8b-hexahydro-1H-4,8a-diaza-as-indacen-3-yl)-4-methyl-benzenesulfonamide 
• 890122-50-6 N-(8-bromo-2-hydroxy-4-methoxy-5-oxo-2,3,3a,4,5,8b-hexahydro-1H-4,8a-diaza-as-indacen-3-yl)-4-methyl-benzenesulfonamide 

Relevant academic research and scientific papers

A stereodivergent strategy to both product enantiomers from the same enantiomer of a stereoinducing catalyst: agelastatin

In this article, we report a full account of our recent development of pyrroles and N-alkoxyamides as new classes of nucleophiles for palladiumcatalyzed AAA reactions, along with application of these methodologies in the total synthesis of agelastatin A,

New class of nucleophiles for palladium-catalyzed asymmetric allylic alkylation. Total synthesis of agelastatin A

New classes of nucleophiles, pyrroles, and N-methoxyamides were developed for Pd-catalyzed AAA reactions. By varying the functional groups at the 2-position of pyrroles, either regioisomer of the piperazinone is available. Using one regioisomer, the total