89019-22-7Relevant academic research and scientific papers
1,2-Acyl Migration to an Electron-deficient Nitrogen Atom: a New Rearrangement of Diaziridines without Ring Opening
Denisenko, Sergei N.,Shustov, Gennady V.,Kostyanovsky, Remir G.
, p. 1275 - 1276 (2007/10/02)
5-Acyl-1,6-diazabicyclohexane (1) on treatment with t-butyl hypochlorite affords the corresponding N-chloro-derivative (2) which rearranges easily into 6-acyl-5-chloro-1,6-diazabicyclohexane (3) with a 1,2-shift of the acyl group.
