89029-49-2Relevant academic research and scientific papers
FUNCTIONALLY SUBSTITUTED ORGANOTIN COMPOUNDS. II. IODODESTANNYLATION OF 1,1-BIS(TRIMETHYLSTANNYL)-1-ALKENES
Mitchell, T. N.,Amamria, A.
, p. 37 - 42 (2007/10/02)
Treatment of 1,1-bis(trimethylstannyl)-1-alkenes with iodine gives mixtures of (E)- and (Z)-1-iodo-1-trimethylstannyl-1-alkenes, the ratio depending on the temperature used.Thermal and photochemical interconversion of these vinylic iodides has been observed.They cannot be used as precursors for the corresponding vinyl Grignard reagents, but undergo bromodestannylation to give the corresponding 1-bromo-1-iodo-1-alkenes.
