89063-85-4Relevant academic research and scientific papers
X=Y-ZH SYSTEM AS POTENTIEL 1,3-DIPOLES. ACTIVATION OF THE ZH PROTON IN IMINES
Grigg, R.,Gunaratne, H. Q. N.,Sridharan, V.,Thianpatanagul, S.,Tute, M.
, p. 4363 - 4366 (1983)
A range of substituents is capable of inducing thermal 1,3-dipole formation in imines (C=N-CH) by activation of the CH proton as shown by trapping experiments with dipolarophiles.
X=Y-ZH SYSTEMS AS POTENTIAL 1,3-DIPOLES. PART 21 ACTIVATION OF THE ZH PROTON IN IMINES.
Grigg, Ronald,Donegan, Gregory,Gunaratne, H. Q. Nimal,Kennedy, Deirdre A.,Malone, John F.,et al.
, p. 1723 - 1746 (2007/10/02)
Imines, RCH=N-ZH, possessing a range of ZH groups (Z=CHCOPh, CHCOSR, CHCONHR, CHP(O)(OEt)2, 2-CH-pyridyl, 2-CH-thiazolyl, and 9-fluorenyl) undergo thermal 1,2-prototropy generating azomethine ylides stereospecifically.The intermediate azomethine ylides un
