891183-12-3Relevant academic research and scientific papers
A new and efficient chemoenzymatic route to both enantiomers of α′-acetoxy and α′-hydroxy-α-methoxy cyclic enones
Demir, Ayhan S.,Caliskan, Zerrin,Aydin, A. Ebru,Bicer, Isil
, p. 786 - 791 (2007/10/03)
A chemoenzymatic synthesis of both enantiomers of the pharmacologically interesting α′-acetoxy and α′-hydroxy-α-methoxy cyclic enones starting from α-hydroxy cyclic enones is described. Protection of 1,2-diketones, manganese(III) acetate-mediated acetoxyl
The α'-oxidation of α-alkoxy enones using manganese(III) acetate in combination with carboxylic acids
Demir,Saatcioglu
, p. 571 - 575 (2007/10/02)
The α'-oxidation of cyclic derivatives of α-alkoxy-α,β-unsaturated ketones using manganese(III)acetate in the presence of various carboxylic acids provided a convenient synthesis of 5-acyloxy-2-alkoxy-2-cyclopentenones and 6-acyloxy-2-alkoxy-2-cyclohexeno
