89173-04-6

Basic information

• Product Name: Re(CO)3(CH₃C₆H₄NC(C₆H₄)NHC₆H₄CH₃)(CH₃C₆H₄NC(C₆H₅)NHC₆H₄CH₃)
• CAS NO: 89173-04-6
• Molecular Weight: 870.037
• Mol File: 89173-04-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Re(CO)3(CH₃C₆H₄NC(C₆H₄)NHC₆H₄CH₃)(CH₃C₆H₄NC(C₆H₅)NHC₆H₄CH₃)(CAS DataBase Reference)
• NIST Chemistry Reference: Re(CO)3(CH₃C₆H₄NC(C₆H₄)NHC₆H₄CH₃)(CH₃C₆H₄NC(C₆H₅)NHC₆H₄CH₃)(89173-04-6)
• EPA Substance Registry System: Re(CO)3(CH₃C₆H₄NC(C₆H₄)NHC₆H₄CH₃)(CH₃C₆H₄NC(C₆H₅)NHC₆H₄CH₃)(89173-04-6)

Safety Data

• Hazardous Substances Data: 89173-04-6(Hazardous Substances Data)

Upstream product

• 14220-21-4 rhenium(I) pentacarbonyl bromide 
• 13471-34-6 N,N'-di-p-tolylbenzamidine 
• 90527-09-6 (Re(CO)4(CH₃C₆H₄NHC(C₆H₅)NC₆H₄CH₃)Cl) 
• 90527-04-1 (Re(CO)4(CH₃C₆H₄NHC(C₆H₅)NC₆H₄CH₃)Br) 

Relevant articles and documents

Amidino-complexes of Rhenium. Bidentate NN'- and ortho-Metallated Derivatives

> complexes (I; R=Me or Ph; R'=Ph or C6H4Me-p), containing delocalised bidentate NN'-chelated amidino-groups, have been prepared by reactions of (i) 2> (X=Cl or Br) with R'N(Li)C(R)NR', (ii) X> with LiBun, (iii) with R'NHC(R)NR', and (iv) by decarbonylation of > complexes.Triphenylphosphine displaces CO from (I) to form > (II), which are more conveniently prepared by the reactions of (L'=PPh3 or AsPh3) with amidines in refluxing toluene.This reaction stops at the intermediate compound Br> when a NNN'-trisubstituted amidine is used.Related complexes Br> are formed when (II) are treated with hydrobromic acid. (X=Cl or Br) and 2> react with amidines to form o-metallated > (R=H, R'=Ph; R''=H; R=Me or Ph, R'=C6H4Me-p, R''=Me; R=Me or Ph, R'=Ph, R''=H) complexes which contain a six-membered o-metallated ring.Benzamidines (R=Ph) produce in addition an isomeric complex in which o-metallation of the R substituent occurs to give complexes having five-membered o-metallated rings.Intermediate 2X> complexes were isolated for R'=C6H4Me-p, R=Me, and X=Cl or Br.A 1,3-proton-shift mechanism for the o-metallation reaction is eliminated by the formation of the complex > (R'=C6H4Me-p) from R'N(Me)C(Me)NR'.Reaction schemes are suggested for the course of the reactions, and structures for the new complexes are proposed on the basis of spectroscopic data.