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Reactions of N,N-dimethylamino(diphenylphosphoryl)chloromethane with alkan-2-ones
Morgalyuk,Strelkova,Nifant'Ev
, p. 1833 - 1835 (2013/11/19)
The direction of the reaction of N,N-dimethylamino(diphenylphosphoryl) chloromethane with alkan-2-ones depends on the ketone structure. N,N-Dimethylamino(diphenylphosphoryl)-chloromethane reacts with linear alkan-2-ones following the Abramov-type reaction to give α-phosphorylated alcohols, while the reaction with branched alkan-2-ones and acetophenone proceeds as the Mannich-type reaction affording the phosphorylated Mannich bases.