891783-10-1

Upstream product

• 108-24-7 acetic anhydride 
• 13139-86-1 4-methoxyphenyl magnesium bromide 
• 38714-70-4 (2R,3R,4R,5S,6S)-2-(acetoxymethyl)-6-(4-methoxyphenyl)tetrahydro-2H-pyran-3,4,5-triyl triacetate 
• 28538-11-6 (1S)-1,5-anhydro-1-(4-methoxyphenyl)-D-glucitol 
• 572-09-8 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide 

Downstream Products

• 891783-11-2 4-(2,3,4-tri-O-acetyl-6-desoxy-β-D-xylo-hex-5-enopyranosyl)anisole 
• 261955-99-1 4-(2,3,4-tri-O-benzyl-6-desoxy-β-D-xylo-hex-5-enopyranosyl)anisole 

Relevant academic research and scientific papers

Triisobutylaluminium (TIBAL) promoted rearrangement of C-glycosides

Triisobutylaluminium-promoted rearrangement of unsaturated glycosides containing electron-donating aglycons, such as C-aryl glycosides, provides direct access to highly functionalised cyclohexane derivatives.

Carbocyclic ring closure of unsaturated S-, Se-, and C-aryl glycosides

Triisobutylaluminum-promoted rearrangement of unsaturated glycosides containing electron-donating aglycons - such as C-aryl glycoside 1, or O-, S- , and Seglycosides - provides direct access to highly functionalized cyclohexane derivatives such as 2.