28538-11-6Relevant articles and documents
Cyanide-Free Synthesis of Glycosyl Carboxylic Acids and Application for the Synthesis of Scleropentaside A
Zou, Liang-Jing,Pan, Qiang,Li, Cai-Yi,Zhang, Ze-Ting,Zhang, Xiao-Wei,Hu, Xiang-Guo
supporting information, p. 8302 - 8306 (2020/11/18)
We have developed a cyanide-free strategy for the synthesis of glycosyl carboxylic acids, which can provide 1,2-trans or 1,2-cis glycosyl carboxylic acids and is compatible with common protecting groups. The synthetic utility was demonstrated by the synth
Triisobutylaluminium (TIBAL) promoted rearrangement of C-glycosides
Sollogoub, Matthieu,Sinay, Pierre
, p. 843 - 858 (2007/10/03)
Triisobutylaluminium-promoted rearrangement of unsaturated glycosides containing electron-donating aglycons, such as C-aryl glycosides, provides direct access to highly functionalised cyclohexane derivatives.
The First Direct Method for C-Glucopyranosyl Derivatization of 2,3,4,6-Tetra-O-benzyl-D-glucopyranose
Allevi, Pietro,Anastasia, Mario,Ciuffreda, Pierangela,Fiecchi, Alberto,Scala, Antonio
, p. 1245 - 1246 (2007/10/02)
Commercially available 2,3,4,6-tetra-O-benzyl-D-glucopyranose, activated by trifluoroacetic anhydride reacts, in the presence of Lewis acids, with various silyl enol ethers or with allylsilane to yield C-D-glucopyranosyl derivatives of the α-configuration