891826-22-5Relevant academic research and scientific papers
Mechanisms of stereocontrol for doubly silylene-bridged Cs- and Cl-symmetric zirconocene catalysts for propylene polymerization. Synthesis and molecular structure of Li2[(1,2-Me2Si)2{C5H
Veghini, Dario,Henling, Lawrence M.,Burkhardt, Terry J.,Bercaw, John E.
, p. 564 - 573 (1999)
Doubly [SiMe2]-bridged metallocenes (1,2-SiMe2)2{η5-C5H 2-4-R}{η5-C5H-3,5-(CHMe2) 2}ZrCl2 (R = H (1a), CHMe2 (1b), SiMesub
An improved synthesis of Kagan's menthyl substituted titanocene and zirconocene dichloride, comparison of their crystal structures, and preliminary catalyst evaluation
Gans?uer, Andreas,Narayan, Sanjay,Schiffer-Ndene, No?llie,Bluhm, Harald,Oltra, J. Enrique,Cuerva, Juan Manuel,Rosales, Antonio,Nieger, Martin
, p. 2327 - 2331 (2006)
An improved synthesis of 1 and 2 is described that allows access to these complexes in multigram quantities necessary for catalytic applications. The crystal structures of 1 and 2 are compared and the conformational preferences of the ligands, that are im
