89184-49-6Relevant articles and documents
Allenylpalladium(II) Species: Possible Intermediates in the Tetrakis(triphenylphosphine)palladium(0)-catalysed Formation of Allenes from Prop-2-ynylic Substrates
Elsevier, Cornelis J.,Kleijn, Henk,Ruitenberg, Klaas,Vermeer, Peter
, p. 1529 - 1530 (1983)
The formation of a 3-methylbuta-1,2-dienylpalladium(II) complex (2) from the prop-2-ynylic chloride (1a) or the prop-2-ynylic acetate (1b) and tetrakis(triphenylphosphine)palladium(0), as well as its conversion into the allenes (4), is described.