Allenylpalladium(II) Species: Possible Intermediates in the Tetrakis(triphenylphosphine)palladium(0)-catalysed Formation of Allenes from Prop-2-ynylic Substrates

DOI: 10.1039/c39830001529

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1529 - 1530 (1983)

Update date:2022-08-04

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Authors:

Elsevier, Cornelis J.

Kleijn, Henk

Ruitenberg, Klaas

Vermeer, Peter

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Article abstract of DOI:10.1039/c39830001529

The formation of a 3-methylbuta-1,2-dienylpalladium(II) complex (2) from the prop-2-ynylic chloride (1a) or the prop-2-ynylic acetate (1b) and tetrakis(triphenylphosphine)palladium(0), as well as its conversion into the allenes (4), is described.

Full text of DOI:10.1039/c39830001529

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