Allenylpalladium(II) Species: Possible Intermediates in the Tetrakis(triphenylphosphine)palladium(0)-catalysed Formation of Allenes from Prop-2-ynylic Substrates

DOI: 10.1039/c39830001529

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1529 - 1530 (1983)

Update date:2022-08-04

Topics:

Authors:

Elsevier, Cornelis J.

Kleijn, Henk

Ruitenberg, Klaas

Vermeer, Peter

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39830001529

The formation of a 3-methylbuta-1,2-dienylpalladium(II) complex (2) from the prop-2-ynylic chloride (1a) or the prop-2-ynylic acetate (1b) and tetrakis(triphenylphosphine)palladium(0), as well as its conversion into the allenes (4), is described.

Full text of DOI:10.1039/c39830001529

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:((CH₃)2CCCH)Pd(P(C₆H₅)3)2Cl

Cas No:89184-49-6

R&D Labs maybe for 89184-49-6

Shandong Jincheng Zhonghua Bio-pharmaceutical Co.,Ltd

Contact:+86-533-5415882

Address:Zichuan Economic Development Zone,Zibo City,Shandong Province,China
Tianjin Boron PharmaTech Co.,Ltd.(expird)

Contact:86-022-59845187

Address:B9-401, Tianda Science Park,No.80,4th Avenue,TEDA,Tianjin, China
BioBioPha Co., Ltd

Contact:+86-871-65217109

Address:132 Lanhei Road, Kunming Institute of Botany, Chinese Academy of Sciences
Suqian Ruixing Chemical Co., Ltd.

Contact:+86-527-80805666（总机）;84836008(销售)

Address:3 Jingsilu, Zone north, Hubin Xincheng Development Park, Suqian, China
TIANJIN DONGRUXIANG MINERALS MARKETING CO.,LTD(expird)

Contact:22-58516360

Address:tianjin

Relevant to this article

Manganese catalyzed cis-dihydroxylation of electron deficient alkenes with H₂O₂

Doi:10.1039/c0ob00102c
(2010)
STRUCTURE OF THIOTROPOCIN, A NEW SULFUR-CONTAINING 7-MEMBERED ANTIBIOTIC

Doi:10.1016/S0040-4039(00)99900-3
(1984)
Glucosylpolyphenols as Inhibitors of Aβ-Induced Fyn Kinase Activation and Tau Phosphorylation: Synthesis, Membrane Permeability, and Exploratory Target Assessment within the Scope of Type 2 Diabetes and Alzheimer's Disease

Doi:10.1021/acs.jmedchem.0c00841
(2020)
Phase-Transfer Synthesis of Symmetrical and Unsymmetrical Dialkyl Trithiocarbonates

Doi:10.1055/s-1986-31819
(1986)
Antibiotics from gliding bacteria. XVIII. The absolute configuration of myxalamide A and B

Doi:10.1002/jlac.198419840109
(1984)
Oxidative Hydrolysis of γ-Thioacetalated Phosphonium Salts. Influence of the Counterion on the Course of the Reaction

Doi:10.1021/jo00185a041
(1984)

Article Doi