89218-25-7Relevant academic research and scientific papers
PREPARATION OPTICALLY ACTIVE α,β-UNSATURATED PHOSPHONATES AND SULFOXIDES FROM PHENYLSULFENYLMETHANEPHOSPHONATES
Koizumi, Toru,Iwata, Masanori,Tanaka, Nobuyuki,Yoshii, Eiichi
, p. 4198 - 4201 (2007/10/02)
The first preparation of optically active α,β-unsaturated phosphonyl compounds from chiral phenylsulfenylmethanephosphonates 1 and 2 has been described.The optically active α,β-unsaturated sulfoxides have also been prepared by the Emmons-Horner reaction of phenylsulfinylmethanephosphonamidate 4 with several aldehydes.KEYWORDS - chiral α,β-unsaturated phosphonate; chiral α,β-unsaturated sulfoxide; absolute configuration; chirality transfer reaction
