892224-19-0Relevant articles and documents
Palladium-catalyzed enantioselective conjugate addition of arylboronic acids
Gini, Francesca,Hessen, Bart,Minnaard, Adriaan J.
, p. 5309 - 5312 (2005)
(Chemical Equation Presented) The first asymmetric palladium-catalyzed conjugate addition of arylboronic acids to α,β-unsaturated aldehydes, ketones, and esters is described. For cyclic substrates, excellent chemo-, regio-, and enantioselectivities are achieved when a Pd(O2CCF 3)2/DuPHOS catalyst is applied.