89249-38-7

Basic information

• Product Name: Benzene, (2-butenylsulfonyl)-, (Z)-
• CAS NO: 89249-38-7
• Molecular Formula: C10H12O2S
• Molecular Weight: 196.27
• Mol File: 89249-38-7.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: Benzene, (2-butenylsulfonyl)-, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (2-butenylsulfonyl)-, (Z)-(89249-38-7)
• EPA Substance Registry System: Benzene, (2-butenylsulfonyl)-, (Z)-(89249-38-7)

Safety Data

• Hazardous Substances Data: 89249-38-7(Hazardous Substances Data)

Upstream product

• 27748-49-8 (Z)-2-nitro-2-butene 
• 873-55-2 sodium benzenesulfonate 
• 13603-84-4 1-(phenylsulfonyl)-2-butyne 
• 884656-75-1 but-3-en-2-yl isobutyl carbonate 
• 24731-39-3 4-(phenylsulfonyl)butan-2-one 
• 38066-16-9 diethyl [(phenylthio)methyl]phosphonate 
• 56069-39-7 diethyl phenylsulfonylmethylphosphonate 
• 74963-80-7 (E)-(but-1-en-1-ylsulfonyl)benzene 
• 598-32-3 2-hydroxy-3-butene 
• 4784-77-4 (E)-1-Bromo-2-butene 
• 702-04-5 crotyl phenyl sulfide 
• 7205-98-3 chloromethyl phenyl sulfone 
• 13610-03-2 but-2-yn-1-yl(phenyl)sulfide 
• 160956-36-5 phenyl 3-(trimethylsilyl)but-3-en-1-yl sulfone 

Relevant articles and documents

Palladium-catalyzed substitution of allylic alcohols with sulfinate salts: A synthesis of bicalutamide

A method is presented for the direct substitution of allylic alcohols with sodium arylsulfinates. The process involves a cooperative action of palladium catalysts, phenylboronic acid and titanium tetraisopropoxide. By taking advantage of this protocol, we achieved a concise synthesis of bicalutamide, an anti-androgen compound for treating prostate cancer.

Oxidative Allylic Esterification of Alkenes by Cooperative Selenium-Catalysis Using Air as the Sole Oxidant

A new metal-free catalysis protocol for the oxidative coupling of nonactivated alkenes with simple carboxylic acids has been established. This method is predicated on the cooperative interaction of a diselane and a photoredox catalyst, which allows for the use of ambient air or pure O2 as the terminal oxidant. Under the title conditions, a range of both functionalized and nonfunctionalized alkenes can be readily converted into the corresponding allylic ester products with good yields (up to 89%) and excellent regioselectivity as well as good functional group tolerance.

α-Sulfonyl succinimides: Versatile sulfinate donors in Fe-catalyzed, salt-free, neutral allylic substitution

Allyl sulfones are versatile intermediates in organic chemistry. The presence of two distinct functional groups sets the stage for a plethora of subsequent transformations. However, despite these advantages the preparation of regioisomerically enriched sulfones is not easy. The use of sulfinate salts as nucleophiles in substitutions is frequently accompanied by side reactions such as π-bond migration, β-elimination, and so on. Herein we present a preparatively simple way to synthesize a variety of different aryl or alkyl allyl sulfones starting from readily accessible allylic carbonates. By employing aryl or alkyl α-sulfonyl succinimides as sulfinate synthons, mild and regioselective ipso substitution of diverse allylic carbonates was realized.