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Some Bifunctional Acylsilanes and Their Photochemical Reactions
Gasking, David I.,Whitham, Gordon H.
, p. 409 - 414 (2007/10/02)
The preparation of the αβ-unsaturated acylsilane (1) and some β-functionalised acylsilanes (2)-(5) is described.On irradiation, the β-azidoacylsilane (2) was converted into the enol form (19) of a β-methyliminoacylsilane, and the β-isothiocyanatoacylsilane (4) underwent isomerisation into the thioamide (23; R = SiMe3).
