89290-01-7Relevant academic research and scientific papers
Optically Active Complexes of Schiff Bases. Part 6. Palladium(II) and Platinum(II) Complexes with Quadridentate Schiff Bases of Salicylaldehyde
Cesarotti, Edoardo,Pasini, Alessandro,Ugo, Renato
, p. 2147 - 2152 (1981)
The synthesis and properties of palladium(II) and platinum(II) complexes with quadridentate Schiff bases derived from the condensation of salicylaldehyde and (R)-1,2-diamines are described.The ligand conformation of the platinum(II) complexes is discussed
PREPARATION AND 1H NMR STUDY OF COMPLEXES OF TRIMETHYLPLATINUM(IV) WITH SOME TRIDENTATE SCHIFF BASE LIGANDS CONTAINING N, O, AND S DONOR ATOMS
Goldsworthy, Duncan H.,Kite, Kenneth
, p. 257 - 264 (1987)
The Schiff base ligands I-V, made by condensing either 2-acetylpyridine (I), 8-quinolinecarboxaldehyde (II and III), or o-methylthiobenzaldehyde (IV and V) with either N,N'-dimethyl-1,3-diaminopropane (I, II, and IV), 2-aminomethylpyridine (III), or 2-(2-aminoethyl)-pyridine (V), give ionic Pt(IV)Me3 complexes containing tridentate NNN- or SNN-bonded ligands.With PtMe3Br ligand V gives a neutral complex XI in which it is coordinated only via the two N atoms.A monomeric Pt(IV)Me3 salicylaldiminate complex results on treating the dimeric trimethylplatinum(IV) salicylaldehyde complex with the bidentate amine H2N(CH2)3NMe2.The complexes have been fully characterised by 1H NMR spectroscopy.
