893418-32-1

Basic information

• Product Name: i-Bu(Cl)AlC₈H₁₇
• Synonyms: i-Bu(Cl)AlC₈H₁₇
• CAS NO: 893418-32-1
• Molecular Weight: 232.773
• Mol File: 893418-32-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: i-Bu(Cl)AlC₈H₁₇(CAS DataBase Reference)
• NIST Chemistry Reference: i-Bu(Cl)AlC₈H₁₇(893418-32-1)
• EPA Substance Registry System: i-Bu(Cl)AlC₈H₁₇(893418-32-1)

Safety Data

• Hazardous Substances Data: 893418-32-1(Hazardous Substances Data)

Upstream product

• 111-66-0 oct-1-ene 
• 1779-25-5 diisobutylaluminum chloride 

Relevant articles and documents

Role of Zr,Al Hydride Intermediate Structure and Dynamics in Alkene Hydroalumination with XAlBui2 (X = H, Cl, Bui), Catalyzed by Zr η5 Complexes

The zirconocene complexes L2ZrCl2 (L = C5H5, C5H4Me, Ind, C5Me5; L2 = rac-Me2C(2-Me-4-But-C5H2)2, meso-Me2C(2-Me-4-But-C5H2)2, rac-Me2C(3-But-C5H3)2, rac-Me2C(Ind)2, rac-Me2Si(Ind)2, and rac-C2H4(Ind)2) were tested as catalysts in alkene hydroalumination by the isobutylalanes XAlBui2 (X = H, Cl, Bui). A low-temperature NMR spectroscopy study on the structure and dynamics of Zr,Al intermediates formed in the L2ZrCl2-XAlBui2 systems showed that the intra- and intermolecular exchange in the bimetallic clusters, controlled by the steric factor of the η5 ligand and organoaluminum compound nature, determines the activity of the whole catalytic system. (Chemical Equation Presented).