89374-84-5Relevant academic research and scientific papers
FORMATION OF PUMMER'S KETONE FROM 4-METHYLPHENOXENIUM ION. AN ACID-CATALYZED SOLVOLYSIS OF N-p-TOLUENESULFONYL-O-(4-TOLYL)HYDROXYLAMINE IN p-CRESOL
Endo, Yasuyuki,Shudo, Koichi,Okamoto, Toshihiko
, p. 3769 - 3770 (2007/10/02)
N-p-ToluenesulfonylO-(4-tolyl)hydroxylamine (1) reacts with p-cresol in the presence of trifluoroacetic acid to yield biscresol (2) and Pummerer's ketone (3). KEYWORDS ---- phenoxenium ion; Pummerer's ketone; oxidation; oxidative coupling
