89389-58-2Relevant academic research and scientific papers
REDUCTIVE SUBSTITUTION OF NICKELOCENE; INTERCEPTION OF A MONOHYDRIDO INTERMEDIATE IN THE HYDROGENATION OF 2,3,4,5-TETRAPHENYLCYCLOPENTADIENONE (TETRACYCLONE)
Slocum, D. W.,Moronski, Marek,Gooding, Richard,Duraj, Stan
, p. C26 - C28 (1984)
Reductive substitution of nickelocene with tetracyclone affords bis(tetracyclone)nickel(0) (1), η3-1,2,3,4-tetraphenyl-5-ketocyclopentenylcyclopentadienylnickel (2) and trans-1,2,3,4-tetraphenylcyclopenten-1-one-5 (3); evidence is presented that 2 is an intermediate in the formation of 3 from 1.
