REDUCTIVE SUBSTITUTION OF NICKELOCENE; INTERCEPTION OF A MONOHYDRIDO INTERMEDIATE IN THE HYDROGENATION OF 2,3,4,5-TETRAPHENYLCYCLOPENTADIENONE (TETRACYCLONE)

DOI: 10.1016/S0022-328X(00)98686-8

Source and publish data:

Journal of Organometallic Chemistry p. C26 - C28 (1984)

Update date:2022-08-03

Topics:

Authors:

Slocum, D. W.

Moronski, Marek

Gooding, Richard

Duraj, Stan

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Article abstract of DOI:10.1016/S0022-328X(00)98686-8

Reductive substitution of nickelocene with tetracyclone affords bis(tetracyclone)nickel(0) (1), η³-1,2,3,4-tetraphenyl-5-ketocyclopentenylcyclopentadienylnickel (2) and trans-1,2,3,4-tetraphenylcyclopenten-1-one-5 (3); evidence is presented that 2 is an intermediate in the formation of 3 from 1.

Full text of DOI:10.1016/S0022-328X(00)98686-8

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