89395-00-6

Basic information

• Product Name: 2,3-epoxyhexan-1-ol
• Synonyms: 2,3-epoxyhexan-1-ol
• CAS NO: 89395-00-6
• Molecular Weight: 116.16
• Mol File: 89395-00-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2,3-epoxyhexan-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3-epoxyhexan-1-ol(89395-00-6)
• EPA Substance Registry System: 2,3-epoxyhexan-1-ol(89395-00-6)

Safety Data

• Hazardous Substances Data: 89395-00-6(Hazardous Substances Data)

Upstream product

• 928-95-0 (E)-2-Hexen-1-ol 

Downstream Products

• 107076-91-5 (2S^*,3S^*)-1-(Benzyloxy)-2,3-epoxyhexane 
• 90454-62-9 (2S,3R)-2-Phenylethynyl-hexane-1,3-diol 
• 90454-61-8 (4S,5R)-1-Phenyl-oct-1-yne-4,5-diol 
• 100992-80-1 (S)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (2S,3S)-3-propyl-oxiranylmethyl ester 
• 66072-21-7 (2RS,3SR)-2-Methylhexane-1,3-diol 
• 62946-67-2 2,3-erythro-3-Methylhexan-1,2-diol 
• 89321-72-2 (S)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (2R,3R)-3-propyl-oxiranylmethyl ester 
• 89321-71-1 (2S,3S)-3-propyl-2-oxiranemethanol 
• 92418-71-8 (2R,3R)-2,3-epoxy-1-hexanol 

Relevant articles and documents

Selective oxidation of alcohols with hydrogen peroxide catalyzed by hexadentate binding 8-quinolinolato manganese(III) complexes

A series of hexadentate 8-quinolinolato manganese(III) complexes were synthesized and proven to own a distorted octahedral geometry via elemental analysis, solid UV-vis spectroscopy and Hartree-Fock/3-21G+ calculation. These Mn(III) complexes were found to be more efficient than their corresponding tetradentate 8-quinolinolato manganese(II) and salen-MnIIIOAc for the oxidation of alcohols in acetone medium, being due to their special hexadentate binding structures that could open an axial Mn{single bond}O bond to form the more active pentadentate structures in the presence of aqueous hydrogen peroxide, as supported by UV-vis spectra. The halogen substituents in ligand's aryl ring could significantly enhance the catalytic activities and 5-chloro-7-iodo-8-quinolinolato manganese(III) gave the highest turnover number (TON). A reasonable mechanism for the present catalytic system was proposed.

Process for cooxidizing organic compounds, process for producing epoxy compounds and process for producing esters or lactones

According to the inventive co-oxidation process of organic compounds, (A) a compound selected from (A1) a compound having a non-aromatic ethylenic bond and (A2) a ketone or an alcohol corresponding to the ketone is oxidized by molecular oxygen in the presence of N-hydroxyphthalimide or another imide compound and in the coexistence of (B) a compound oxidizable by the imide compound and oxygen and different from the compound (A). As the compound (B), (a) primary or secondary alcohols (e.g., benzhydrol, cyclohexanol), (b) compounds each having a carbon-hydrogen bond at the adjacent position to an unsaturated bond (e.g., tetralin, ethylbenzene) and the like can be used. According to this process, a corresponding epoxy compound from the compound (A1) having a non-aromatic ethylenic bond, and a corresponding ester or lactone from the ketone or its corresponding alcohol (A2) can be obtained in satisfactory yields.