107076-91-5Relevant articles and documents
Cesium propionate as an epoxide cleavage and inversion reagent
Arbelo, David O,Prieto, José A
, p. 4111 - 4114 (2002)
A new epoxide inversion method, based on cesium propionate as the epoxide-cleaving agent, was developed. The initial epoxide-cleavage reaction produced a pair of regioisomeric propionates that were mesylated and methanolyzed to produce the inverted epoxide. Several new epoxides were prepared by this method, including 3,4-epoxy alcohols, which are important precursors for polypropionate synthesis.
Useful base promoted elaborations of oxiranyl ethers
Thurner, Angelika,Faigl, Ferenc,Toke, László,Mordini, Alessandro,Valacchi, Michela,Reginato, Gianna,Czira, Gábor
, p. 8173 - 8180 (2007/10/03)
Functionalized oxiranyl ethers can be regio- and stereoselectively converted into hydroxy oxetanes or cis-diols by treatment with organometallic bases. These two rearrangements can be conveniently carried out either using different reaction conditions sta
Regiochemical Control of the Ring Opening of 1,2-Epoxides by Means of Chelating Processes. 5. Synthesis and Reactions of Some 2,3-Epoxy-1-alkanol Derivatives
Chini, Marco,Crotti, Paolo,Flippin, Lee A.,Gardelli, Christina,Giovani, Elena,et al.
, p. 1221 - 1227 (2007/10/02)
In order to study the effect of a remote polar functionality on the regiochemistry of the ring opening of aliphatic epoxides, the synthesis and some nucleophilic additions (methanolysis, azidolysis, and aminolysis) of suitable 2,3-epoxy-1-alkanol derivati
