89459-98-3Relevant articles and documents
A critical outlook and comparison of enantioselective oxidation methodologies of olefins
Bonini, Carlo,Righi, Giuliana
, p. 4981 - 5021 (2002)
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Amino Acids and Peptides; 70. Optically Active α-Amino Acids, N-Boc-Aminoaldehydes and α-Amino-β-hydroxy Acids from 2,3-Epoxy Alcohols
Schmidt, Ulrich,Respondek, Mathias,Lieberknecht, Albrecht,Werner, Juergen,Fischer, Peter
, p. 256 - 261 (2007/10/02)
Trichloroacetimidic esters of 2,3-epoxy alcohols are transformed into oxazolines 5 and dihydrooxazines 6, respectively, depending on the structure of the educts and the catalyst.The five-membered ring compounds 5 are transformed into erythro-α-amino-β-hydroxy acids (60-70percent from epoxy alcohols) via axazolidinones 11, 12, and 13. α-Amino acids and α-substituted α-amino acids 10 as well as the corresponding aldehydes 9 are obtained from the dihydrooxazines 6 (50-60percent from epoxy alcohols).