89464-19-7Relevant academic research and scientific papers
PROCESS TO PREPARE EPSILON-CAPROLACTAM
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, (2014/10/18)
The invention is directed to a process to prepare ε-caprolactam and/or unsaturated ε-caprolactam from a pentenamide by contacting the pentenamide with a mixture of hydrogen and carbon monoxide in the presence of a solvent and a catalyst system comprising of a Group 8-10 metal and a phosphorus-donor ligand. The ligand may be a xantphos-type ligand.
Pyrolytic study of cyclic 2-azidoketones
Chou, Chin-Hsing,Chu, Li-Tse,Chen, I-Ying,Wu, Bo-Jian
, p. 577 - 582 (2008/09/20)
Flash vacuum pyrolysis of 2-azidocyclohexanone (1) gave a condensed dimer (6), a ring expanded product (7) and 2-methylpyridine (8). On the other hand, pyrolysis of 2-azidocyclopentanone (4) and 2-azidocycloheptanone (5) gave ring expanded products (12) and (13), respectively, as the main products.
