894806-14-5

Basic information

• Product Name: (2Z)-6-bromo-3,7-dimethyl-7-methoxyoct-2-en-1-ol
• Synonyms: (2Z)-6-bromo-3,7-dimethyl-7-methoxyoct-2-en-1-ol
• CAS NO: 894806-14-5
• Molecular Weight: 265.191
• Mol File: 894806-14-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2Z)-6-bromo-3,7-dimethyl-7-methoxyoct-2-en-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (2Z)-6-bromo-3,7-dimethyl-7-methoxyoct-2-en-1-ol(894806-14-5)
• EPA Substance Registry System: (2Z)-6-bromo-3,7-dimethyl-7-methoxyoct-2-en-1-ol(894806-14-5)

Safety Data

• Hazardous Substances Data: 894806-14-5(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 79-21-0 peracetic acid 
• 106-25-2 Nerol 

Downstream Products

• 1786-08-9 3,6-dihydro-4-methyl-2-(2-methyl-1-propenyl)–2H-pyran 

Relevant articles and documents

A useful propionate cofactor enhancing activity for organic solvent-tolerant recombinant metal-free bromoperoxidase (perhydrolase) from Streptomyces aureofaciens

The oxidative brominating activity of an organic solvent-tolerant recombinant metal-free bromoperoxidase BPO-A1 with C-terminal His-tag (rBPO-A1), from Streptomyces aureofaciens found to depend on various additives. These included carboxylic acids, used as cofactors and alcohols, used as water-miscible organic solvents. Enzyme activity was significantly enhanced by using propanoic acid (PA) as a cofactor, which had a high Log D at pH 5.0 and ethylene glycol with a low Log P. The positional specificity of oxidative hydroxybromination for olefins, using rBPO-A1 and PA in the presence of methanol, was higher compared to a non-enzymatic reaction using peracetic acid. The oxidative bromination step, occurring after enzymatic peroxidation step, is suggested to be pseudoenzymatic.