89486-30-6Relevant academic research and scientific papers
1,2-disiladioxetanes: Structure, rearrangement, and reactivity
McKillop, Kirsten L.,Gillette, Gregory R.,Powell, Douglas R.,West, Robert
, p. 5203 - 5208 (2007/10/02)
The low-temperature reaction of (E)-1,2-dimesityl-1,2-di-tert-butyldisilene (1a) with dioxygen gives (E)-1,2-dimesityl-1,2-di-tert-butyldisiladioxetane (2a), the structure of which has been established by X-ray crystallographic analysis. This result estab
Formation of a Disiloxirane in the Oxidation of 1,2-Dimesityl-1,2-di-t-butyldisilaethylene
Michalczyk, Michael J.,West, Robert,Michl, Josef
, p. 1525 - 1526 (2007/10/02)
Reaction of trans-1,2-di-t-butyl-1,2-dimesityldisilaethylene in solution with dioxygen at -78 deg C produces the disiloxirane (7) and a compound believed to be the 1,2-disiladioxetane (8a); the latter compound rearranges quantitatively to the known 1,3-cyclodisiloxane (5) above 0 deg C.
