95206-58-9Relevant academic research and scientific papers
1,2-disiladioxetanes: Structure, rearrangement, and reactivity
McKillop, Kirsten L.,Gillette, Gregory R.,Powell, Douglas R.,West, Robert
, p. 5203 - 5208 (2007/10/02)
The low-temperature reaction of (E)-1,2-dimesityl-1,2-di-tert-butyldisilene (1a) with dioxygen gives (E)-1,2-dimesityl-1,2-di-tert-butyldisiladioxetane (2a), the structure of which has been established by X-ray crystallographic analysis. This result estab
THREE-, FOUR- AND FIVE-MEMBERED RINGS FROM DISILENES
West, Robert,Gillette, Gregory R.,Yokelson, H. B.,Millevolte, A. J.
, p. 3 - 14 (2007/10/02)
Disilenes, R2Si=SiR2, react with many substances to produce cyclic compounds containing two silicon atoms and one or more heteroatoms.Most of these products are new ring systems, and some show abnormal structures with short Si-Si bonds, suggesting unusual chemical bonding.
Formation of a Disiloxirane in the Oxidation of 1,2-Dimesityl-1,2-di-t-butyldisilaethylene
Michalczyk, Michael J.,West, Robert,Michl, Josef
, p. 1525 - 1526 (2007/10/02)
Reaction of trans-1,2-di-t-butyl-1,2-dimesityldisilaethylene in solution with dioxygen at -78 deg C produces the disiloxirane (7) and a compound believed to be the 1,2-disiladioxetane (8a); the latter compound rearranges quantitatively to the known 1,3-cyclodisiloxane (5) above 0 deg C.
