89486-57-7

Basic information

• Product Name: Benzene, [(1R,2S)-2-(2-methyl-1-propenyl)cyclopropyl]-, rel-
• CAS NO: 89486-57-7
• Molecular Formula: C13H16
• Molecular Weight: 172.27
• Mol File: 89486-57-7.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzene, [(1R,2S)-2-(2-methyl-1-propenyl)cyclopropyl]-, rel-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(1R,2S)-2-(2-methyl-1-propenyl)cyclopropyl]-, rel-(89486-57-7)
• EPA Substance Registry System: Benzene, [(1R,2S)-2-(2-methyl-1-propenyl)cyclopropyl]-, rel-(89486-57-7)

Safety Data

• Hazardous Substances Data: 89486-57-7(Hazardous Substances Data)

Upstream product

• 200137-58-2 (E)-5-Methylselanyl-5-phenyl-pent-2-enoic acid methyl ester 
• 200137-56-0 3-Methylselanyl-3-phenyl-propionaldehyde 
• 14371-10-9 (E)-3-phenylpropenal 
• 100-42-5 styrene 
• 4544-23-4 1-(2'-methylpropenylidene)-2-phenylcyclopropane 
• 15874-80-3 3-methyl-1-(phenylsulfonyl)but-2-ene 
• 107-86-8 3,3-dimethyl acrylaldehyde 

Relevant articles and documents

The Heterogeneous Catalytic Hydrogenation of Cumulated Allene-cyclopropanes: 1-(2'-Methylpropenylidene)-2-phenylcyclopropane.

The unsymmetrical title compound 2 having phenyl as an activating substituent was hydrogenated in heterogeneous solution phase using supported platinum and palladium as well as Raney nickel catalysts. Data are presented graphically using 'snapshot analysi

Conversion of non-activated alkenes into cyclopropanes with lithiated sulfones under nickel catalysis

Summary -Lithiated alkyl ierf-butyl sulfones convert alkenes into cyclopropane derivatives under nickel catalysis. The new reaction appears to differ from the known cyclopropanation reactions from both the stereochemical and the electronic points of view. Elsevier.