89496-80-0Relevant academic research and scientific papers
OPTICALLY ACTIVE CYCLIC ALLYLSILANES PREPARATION BY ASYMMETRIC HYDROSILYLATION AND ANTI STEREOCHEMISTRY IN SE' REACTIONS
Hayashi, Tamio,Kabeta, Keiji,Yamamoto, Tsunehiro,Tamao, Kohei,Kumada, Makoto
, p. 5661 - 5664 (1983)
Reaction of optically active cyclic allylsilanes, (S)-3-(trimethylsilyl)cyclopentene and -cyclohexene, wich were prepared by palladium-catalyzed asymmetric hydrosilylation of cyclic dienes, with ethylene oxide in the presence of titanium chloride proceeded with anti stereochemistry to give (R)-3-(2-hydroxyethyl)cyclopentene and -cyclohexene, respectively.
