OPTICALLY ACTIVE CYCLIC ALLYLSILANES PREPARATION BY ASYMMETRIC HYDROSILYLATION AND ANTI STEREOCHEMISTRY IN SE' REACTIONS

DOI: 10.1016/S0040-4039(00)94167-4

Source and publish data:

Tetrahedron Letters p. 5661 - 5664 (1983)

Update date:2022-08-03

Topics:

Authors:

Hayashi, Tamio

Kabeta, Keiji

Yamamoto, Tsunehiro

Tamao, Kohei

Kumada, Makoto

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Article abstract of DOI:10.1016/S0040-4039(00)94167-4

Reaction of optically active cyclic allylsilanes, (S)-3-(trimethylsilyl)cyclopentene and -cyclohexene, wich were prepared by palladium-catalyzed asymmetric hydrosilylation of cyclic dienes, with ethylene oxide in the presence of titanium chloride proceeded with anti stereochemistry to give (R)-3-(2-hydroxyethyl)cyclopentene and -cyclohexene, respectively.

Full text of DOI:10.1016/S0040-4039(00)94167-4

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