89506-21-8

Basic information

• Product Name: bromo(N-methyl-3,4-dimethoxybenzalimine-6,C,N)triphenylphosphinepalladium(II)
• Synonyms: bromo(N-methyl-3,4-dimethoxybenzalimine-6,C,N)triphenylphosphinepalladium(II)
• CAS NO: 89506-21-8
• Molecular Weight: 626.826
• Mol File: 89506-21-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: bromo(N-methyl-3,4-dimethoxybenzalimine-6,C,N)triphenylphosphinepalladium(II)(CAS DataBase Reference)
• NIST Chemistry Reference: bromo(N-methyl-3,4-dimethoxybenzalimine-6,C,N)triphenylphosphinepalladium(II)(89506-21-8)
• EPA Substance Registry System: bromo(N-methyl-3,4-dimethoxybenzalimine-6,C,N)triphenylphosphinepalladium(II)(89506-21-8)

Safety Data

• Hazardous Substances Data: 89506-21-8(Hazardous Substances Data)

Upstream product

• 89525-44-0 N-methyl-3,4-dimethoxy-6-bromobenzalimine 
• 32005-36-0 bis(dibenzylideneacetone)-palladium⁽⁰⁾ 
• 14221-01-3 tetrakis(triphenylphosphine) palladium⁽⁰⁾ 
• 89506-15-0 di-μ-bromobis(N-methyl-3,4-dimethoxybenzalimine-6,C,N)dipalladium(II) 

Relevant articles and documents

PALLADIUM ASSISTED ORGANIC REACTIONS. VI. A NEW METHOD FOR THE PREPARATION OF CYCLOPALLADATED BENZALIMINES

A new, improved method is described for the preparation of cyclopalladated benzalimines; it consists of reacting the ortho-bromobenzalimine with bis(dibenzylideneacetone)palladium(0).A number of substituted o-bromobenzalimines has been studied; the bridged bromide dimers and the corresponding bromo(N-substituted benzalimine-6,C,N)triphenylphosphinepalladium(II) complexes have been fully characterised and 1H and 13C NMR spectral data recorded.In the cases of the N-phenylbenzalimines studied, bis(triphenylphosphine) complexes were also isolated and characterised.