895138-95-1

Basic information

• Product Name: [Os(κ2-dimethyldithiocarbamate)(SiCl3)(CO)(PPh3)2]
• CAS NO: 895138-95-1
• Molecular Weight: 997.456
• Mol File: 895138-95-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Os(κ2-dimethyldithiocarbamate)(SiCl3)(CO)(PPh3)2](CAS DataBase Reference)
• NIST Chemistry Reference: [Os(κ2-dimethyldithiocarbamate)(SiCl3)(CO)(PPh3)2](895138-95-1)
• EPA Substance Registry System: [Os(κ2-dimethyldithiocarbamate)(SiCl3)(CO)(PPh3)2](895138-95-1)

Safety Data

• Hazardous Substances Data: 895138-95-1(Hazardous Substances Data)

Upstream product

• 56800-92-1 [Os(κ2-dimethyldithiocarbamate)H(CO)(PPh3)2] 
• 10025-78-2 trichlorosilane 

Relevant articles and documents

The structurally characterised silyl complexes, Os(κ2-S2CNMe2)(SiMeCl2)(CO)(PPh3)2 and Os(κ2-S2CNMe2)(SiCl3)(CO)(PPh3)2, which have remarkably unreactive Si-Cl bonds

Treatment of Os(κ2-S2CNMe2)H(CO)(PPh3)2 with HSiMeCl2 or HSiCl3 gives in high yield Os(κ2-S2CNMe2)(SiMeCl2)(CO)(PPh3)2 (1) or Os(κ2-S2CNMe2)(SiCl3)(CO)(PPh3)2 (2), respectively. The crystal structures of both compounds have been determined and the Os-Si distances are 2.3672(10) A? for 1 and 2.3449(12) A? for 2. In solution, and under forcing conditions, both compounds are extraordinarily unreactive towards hydroxide ions.