89523-70-6Relevant academic research and scientific papers
Kinetic Resolution of Allyltriflamides through a Pd-Catalyzed C-H Functionalization with Allenes: Asymmetric Assembly of Tetrahydropyridines
González, José Manuel,Cendón, Borja,Mascare?as, José Luis,Gulías, Moisés
supporting information, p. 3747 - 3752 (2021/04/06)
Enantioenriched, six-membered azacycles are essential structural motifs in many products of pharmaceutical or agrochemical interest. Here we report a simple and practical method for enantioselective assembly of tetrahydropyridines, which is paired to a ki
STEREOSELECTIVITY IN THE HYDROBORATION OF CHIRAL CYCLOHEXANE-DERIVED ALLYLIC ALCOHOLS
Birtwistle, David H.,Brown, John M.,Foxton, Michael W.
, p. 4367 - 4370 (2007/10/02)
The isomeric 2-ethylidenecyclohexanols are hydroborated by t-hexylborane with weak stereoselectivity whilest 1-(1'-hydroxyalkyl)cyclohexenes show up to 50:1 discrimination.
SELECTIVE GRIGNARD-TYPE CARBONYL ADDITION OF ALKENYL HALIDES MEDIATED BY CHROMIUM(II) CHLORIDE
Takai, Kazuhiko,Kimura, Keizo,Kuroda, Tooru,Hiyama, Tamejiro,Nozaki, Hitosi
, p. 5281 - 5284 (2007/10/02)
Alkenyl (or aryl) iodide (or bromide) is readily reduced with CrCl2 in N,N-dimethylformamide at 25oC to give the corresponding organochromium species which adds selectively to an aldehyde moiety without affecting the coexisting ketone or cyano group of the substrate.
