895567-35-8

Upstream product

• 85272-30-6 diisopropylsilanediyl bistriflate 
• 101712-01-0 (R)-1-((R)-4-benzyl-2-oxooxazolidin-3-yl)-2-methylpentane-1,3-dione 
• 141505-93-3 (2R,4S,5S)-1-((R)-4-Benzyl-2-oxo-oxazolidin-3-yl)-5-hydroxy-2,4,6-trimethyl-hept-6-ene-1,3-dione 

Downstream Products

• 895567-37-0 (R)-4-Benzyl-3-{(R)-2-[(4R,5S,6R)-6-((1R,2R,3S,5R,6S)-2,6-dihydroxy-1,3,5-trimethyl-4-oxo-octyl)-2,2-diisopropyl-5-methyl-[1,3,2]dioxasilinan-4-yl]-propionyl}-oxazolidin-2-one 
• 895567-38-1 (R)-4-Benzyl-3-((R)-2-{(4R,5S,6S)-6-[(S)-1-(6-ethyl-3,5-dimethyl-4-oxo-4H-pyran-2-yl)-ethyl]-2,2-diisopropyl-5-methyl-[1,3,2]dioxasilinan-4-yl}-propionyl)-oxazolidin-2-one 
• 895567-36-9 (S)-2-{(4S,5S,6R)-6-[(R)-2-((R)-4-Benzyl-2-oxo-oxazolidin-3-yl)-1-methyl-2-oxo-ethyl]-2,2-diisopropyl-5-methyl-[1,3,2]dioxasilinan-4-yl}-propionaldehyde 

Relevant academic research and scientific papers

Stereoselective synthesis and cyclisation of the acyclic precursor to auripyrone A and B

The acyclic precursor to the auripyrones has been synthesized by a stereoselective aldol strategy. This compound fails to undergo cyclisation to form the spiroacetal dihydropyrone ring system found in auripyrone A and B; instead, it forms a dihydropyrone