89557-24-4

Upstream product

• 501085-40-1 rac-ethyl trans-6-[(tert-butoxycarbonyl)amino]-5-hydroxycyclohexa-1,3-diene-1-carboxylate 
• 501085-41-2 (1R,2S,3S,4S)-3-tert-Butoxycarbonylamino-7-oxa-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid ethyl ester 
• 84751-41-7 ethyl (1SR,2RS,3RS,4RS)-3-nitro-7-oxabicyclo[2.2.1]hept-5-ene-2-carboxylate 
• 58632-95-4 2-(tert-Butoxycarbonyloxyimino)-2-phenylacetonitrile 

Downstream Products

• 89616-67-1 (5S,6S)-6-tert-Butoxycarbonylamino-5-hydroxy-cyclohexa-1,3-dienecarboxylic acid methyl ester 
• 501085-42-3 tert-butyl(2'S,5S,6S)-(+)-2'-[6-tert-butoxycarbonylamino-5-hydroxycyclohexa-1,3-diene-1-carbonyloxy]propionate 
• 89557-25-5 2-((1S,6S)-6-tert-Butoxycarbonylamino-5-methoxycarbonyl-cyclohexa-2,4-dienyloxy)-2-dimethylaminomethyl-malonic acid dimethyl ester 
• 89616-69-3 (5S,6S)-6-tert-Butoxycarbonylamino-5-(1-methoxycarbonyl-vinyloxy)-cyclohexa-1,3-dienecarboxylic acid methyl ester 
• 89616-68-2 2-((1S,6S)-6-tert-Butoxycarbonylamino-5-methoxycarbonyl-cyclohexa-2,4-dienyloxy)-malonic acid dimethyl ester 

Relevant academic research and scientific papers

Asymmetric synthesis of the putative structure of (-)-oryzoxymycin.

[reaction: see text] A short asymmetric synthesis of (2'S,5R,6R)-2'-[6-amino-5-hydroxy-1,3-cyclohexadiene-1-carbonyloxy]propionic acid, the enantiomer of the reported structure of (+)-oryzoxymycin is described. The reported spectral data does not match that obtained for synthetic "oryzoxymycin".