501085-40-1

Upstream product

• 140-88-5 ethyl acrylate 
• 84751-41-7 ethyl (1SR,2RS,3RS,4RS)-3-nitro-7-oxabicyclo[2.2.1]hept-5-ene-2-carboxylate 
• 5941-50-4 (E)-ethyl 3-nitroacrylate 
• 501085-41-2 (1R,2S,3S,4S)-3-tert-Butoxycarbonylamino-7-oxa-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid ethyl ester 

Downstream Products

• 501085-42-3 tert-butyl(2'S,5S,6S)-(+)-2'-[6-tert-butoxycarbonylamino-5-hydroxycyclohexa-1,3-diene-1-carbonyloxy]propionate 
• 89557-24-4 (5S,6S)-6-tert-Butoxycarbonylamino-5-hydroxy-cyclohexa-1,3-dienecarboxylic acid 

Relevant academic research and scientific papers

Asymmetric synthesis of the putative structure of (-)-oryzoxymycin.

[reaction: see text] A short asymmetric synthesis of (2'S,5R,6R)-2'-[6-amino-5-hydroxy-1,3-cyclohexadiene-1-carbonyloxy]propionic acid, the enantiomer of the reported structure of (+)-oryzoxymycin is described. The reported spectral data does not match that obtained for synthetic "oryzoxymycin".