89563-22-4Relevant academic research and scientific papers
1,3-Oxathiole-2-thiones from the Reaction of Carbon Disulfide with Zwitterionic Iodonium Compounds
Papadopoulou, Maria,Spyroudis, Spyros,Varvoglis, Anastasios
, p. 1509 - 1511 (2007/10/02)
We have synthesized 1,3-oxathiole-2-thiones from the reaction of zwitterionic iodonium compounds with carbon disulfide.The reaction is shown to be photochemical and possible pathways are discussed.
Synthesis and Reactivity of 2-Oxidodiaryliodonium Zwitterions
Spyroudis, Spyros,Varvoglis, Anastasios
, p. 135 - 137 (2007/10/02)
The direct synthesis of three new 2-oxidoaryliodonium zwitterions from phenols and aryliodine(III) bistrifluoroacetate and their reaction with nucleophiles and electrophiles are reported.Especially noteworthy is the reactivity of 2-methoxy-3,5-dinitrophenyl(phenyl)iodonium tetrafluoroborate (15) which is hydrolysed by water and solvolysed by alcohols at room temperature.
