89566-74-5Relevant academic research and scientific papers
Inversion of Configuration at the Phosphorus Nucleophile in the Diastereoselective and Enantioselective Synthesis of P-Stereogenic syn-Phosphiranes from Chiral Epoxides
Muldoon, Jake A.,Varga, Balázs R.,Deegan, Meaghan M.,Chapp, Timothy W.,E?rd?gh, ádám M.,Hughes, Russell P.,Glueck, David S.,Moore, Curtis E.,Rheingold, Arnold L.
supporting information, p. 5047 - 5051 (2018/03/27)
Nucleophilic substitution results in inversion of configuration at the electrophilic carbon center (SN2) or racemization (SN1). The stereochemistry of the nucleophile is rarely considered, but phosphines, which have a high barrier to
Reaction of lithium (2,4,6-tri-tert-butylphenyl)silylphosphides with haloforms
Sasaki, Shigeru,Yoshifuji, Masaaki,Inamoto, Naoki
experimental part, p. 15 - 23 (2012/03/08)
The reaction of lithium (tert-butyldimethylsilyl)(2,4,6-tri-tert- butylphenyl)phosphide with chloroform afforded (Z)-2-(tert-butyldimethylsilyl)- 2-chloro-1-(2,4,6-tri-tert-butylphenyl)-1- phosphaethene. The NMR study revealed a secondary phosphine result
REACTION OF A DIPHOSPHENE WITH BUTYLLITHIUM
Yoshifuji, Masaaki,Shibayama, Katsuhiro,Inamoto, Naoki
, p. 115 - 118 (2007/10/02)
1,2-Bis(2,4,6-tri-t-butylphenyl)diphosphene reacted with butyllithium to give 1-alkyl-2-butyl-1,2-bis(2,4,6-tri-t-butylphenyl)diphosphanes after quenching with various alkyl halides, sulfurization of which afforded diphosphane monosulfides.
