89577-09-3Relevant articles and documents
Addition reactions of nitryl chloride at multiple bonds
Zyk,Bondarenko,Nesterov,Zefirov
, p. 980 - 986 (2007/10/03)
Published data on additio of nitryl chloride to alkenes and possible reaction mechanisms were analyzed. Reactions of nitryl chloride with alkenes differing in the ionization potentials of the double bond and in the abilities to undergo various structural rearrangements were studied. Nitryl chloride was shown to be very sensitive both to the substrate and to the reaction conditions.
Acetal Chlorination with MnO2-Trimethylchlorosilane
Bellesia, Franco,Boni, Monica,Ghelfi, Franco,Grandi, Romano,Pagnoni, Ugo M.,Pinetti, Adriano
, p. 4579 - 4586 (2007/10/02)
α-Chloroacetals are obtained in almost quantitative yields, by treating acetals with MnO2-trimethylchlorosilane in CH3OH:CH3CN (1:1).The halogenation is explained by a ligand-transfer process on an enolether intermediate, mediated by a Mn(IV)-chloride species.Key Words: Acetals, Aldehydes, Chlorination, Maganese(IV)oxide, Trimethylchlorosilane, Ligand-transfer
CHLORINATION OF ALKENES BY MANGANESE(III) CHLORIDE SPECIES
Donnelly, K. D.,Fristad, W. E.,Gellerman, B. J.,Peterson, J. R.,Selle, B. J.
, p. 607 - 610 (2007/10/02)
Several manganese(III) chloride species have been prepared in situ and used as effective chlorinating agents of alkenes.