89577-09-3

Usage

Uses

Used in Organic Synthesis:
Bicyclo[2.2.1]heptane, 2,3-dichloro-, (endo,endo)(9CI) is utilized as a building block in organic synthesis for the creation of more complex molecules. Its unique structure and properties make it a valuable component in the synthesis of various organic compounds.
Used in Research Laboratories:
Bicyclo[2.2.1]heptane, 2,3-dichloro-, (endo,endo)(9CI) is also employed in research laboratories for studying its properties and potential applications. The presence of chlorine atoms allows researchers to explore its reactivity and behavior in different chemical reactions.
Used in Pharmaceutical Industry:
Bicyclo[2.2.1]heptane, 2,3-dichloro-, (endo,endo)(9CI) may have potential applications in the pharmaceutical industry, where it could be used as a precursor or intermediate in the development of new drugs. Its unique structure and properties could contribute to the discovery of novel therapeutic agents.
Used in Agrochemicals:
Additionally, Bicyclo[2.2.1]heptane, 2,3-dichloro-, (endo,endo)- (9CI) may find use in the agrochemical sector, where it could be employed in the synthesis of pesticides, herbicides, or other agricultural chemicals. Its potential applications in this field are currently under exploration.
Safety Precautions:
It is crucial to handle Bicyclo[2.2.1]heptane, 2,3-dichloro-, (endo,endo)(9CI) with proper safety measures, as the chlorine atoms in its structure may pose health and environmental risks if not managed correctly. Appropriate handling, storage, and disposal procedures should be followed to minimize any potential hazards.

Upstream product

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• 2843-35-8 trans-5,6-dichlorobicyclo<2.2.1>hept-2-ene 
• 108-24-7 acetic anhydride 
• 542-92-7 cyclopenta-1,3-diene 

Relevant academic research and scientific papers

Addition reactions of nitryl chloride at multiple bonds

Published data on additio of nitryl chloride to alkenes and possible reaction mechanisms were analyzed. Reactions of nitryl chloride with alkenes differing in the ionization potentials of the double bond and in the abilities to undergo various structural rearrangements were studied. Nitryl chloride was shown to be very sensitive both to the substrate and to the reaction conditions.

A Structurally Characterized Dichloro-manganese(IV) Complex Capable of Halogenating Alkenes

MnIV(salpn)Cl2 regioselectively trans-halogenates alkenes in a reaction for which the Mn-containing product is also identified; this is the first Mn-based halogenating system for which the reactive and final Mn-containing products are structurally characterized.

Acetal Chlorination with MnO2-Trimethylchlorosilane

α-Chloroacetals are obtained in almost quantitative yields, by treating acetals with MnO2-trimethylchlorosilane in CH3OH:CH3CN (1:1).The halogenation is explained by a ligand-transfer process on an enolether intermediate, mediated by a Mn(IV)-chloride species.Key Words: Acetals, Aldehydes, Chlorination, Maganese(IV)oxide, Trimethylchlorosilane, Ligand-transfer

CHLORINATION OF ALKENES BY MANGANESE(III) CHLORIDE SPECIES

Several manganese(III) chloride species have been prepared in situ and used as effective chlorinating agents of alkenes.

ROLE OF THE POLYMER BACKBONE ON THE REACTIVITY OF POLYMER-SUPPORTED (DICHLOROIODO)BENZENE

Chlorination of iodinated crosslinked polystyrene with Cl2 gave polyaryliododichloride containing 1.1 mmol of active chlorine per gram of resin, while fluorination of the same iodinated resin with XeF2 gave polyaryliododifluoride, co