89593-86-2

Upstream product

• 89593-91-9 C₁₆H₁₇ClS₂ 
• 3561-67-9 bis(phenylthio)methane 
• 89593-85-1 C₁₆H₁₇ClO₄S₂ 

Downstream Products

• 118736-30-4 1,1-bis(benzenesulphonyl)-4-(3-chlorobenzenethio)butane 
• 28246-89-1 1,1-bis(benzenesulphonyl)cyclobutane 
• 118736-33-7 1,1-bis(benzenesulphonyl)-4-(4-methylbenzenethio)butane 
• 118736-29-1 1,1-bis(benzenesulphonyl)-4-(benzenethio)butane 
• 118736-32-6 1,1-bis(benzenesulphonyl)-4-(3-methylbenzenethio)butane 
• 118736-31-5 1,1-bis(benzenesulphonyl)-4-(3-methoxybenzenethio)butane 

Relevant academic research and scientific papers

Elimination and Addition Reactions. Part 40. The Insignificant Effect of Strain in Higher Order Eliminations in 1,1-bis(phenylsulphonyl) Carbanions with ω-Leaving Groups

Rates of cyclisation of 1,1-bis(phenylsulphonyl) carbanions bearing distal leaving groups have been determined.The response of the system to solvent effects and to leaving group is similar to that in intramolecular nucleophilic substitution.The system is

Activation Parameters for Intramolecular Nucleophilic Substitution by Carbanions - the Insignificant Effect of Ring Strain on Cylisation Rates

Activation parameters for the cyclisation of bis-sulphonyl-stabilised carbanions to bis-sulphonylcycloalkanes have been determined; cyclopropanes form nearly a million-fold faster than cyclobutanes and ring strain is a negligible factor in determining rea