89618-51-9Relevant academic research and scientific papers
First photosubstitution chemistry of fulvalene-bridged metal-metal bonded carbonyls. Synthesis and structural determination of novel homo- and heterobimetallic alkyne complexes
Drage, James S.,Tilset, Mats,Vollhardt, Peter C.,Weidman, Timothy W.
, p. 812 - 814 (1984)
Irradiation of the carbonyl(η5:η5-fulvalene)di-metal complexes of molybdenum, tungsten, and ruthenium 1, 3, and 4 in the presence of alkynes gives not only complexes of different respective composition and structure within the series but also in comparison with the corresponding (η5-cyctopentadienyl)metal carbonyl dimers. (η5:η5-C10H8)(CO) 5MoRu (5) furnishes a novel reactive dinuclear (alkyne)metal oxo complex.
