Organometallics p. 812 - 814 (1984)
Update date:2022-08-03
Topics:
Drage, James S.
Tilset, Mats
Vollhardt, Peter C.
Weidman, Timothy W.
Irradiation of the carbonyl(η5:η5-fulvalene)di-metal complexes of molybdenum, tungsten, and ruthenium 1, 3, and 4 in the presence of alkynes gives not only complexes of different respective composition and structure within the series but also in comparison with the corresponding (η5-cyctopentadienyl)metal carbonyl dimers. (η5:η5-C10H8)(CO) 5MoRu (5) furnishes a novel reactive dinuclear (alkyne)metal oxo complex.
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