89618-90-6

Upstream product

• 358-23-6 trifluoromethylsulfonic anhydride 
• 89619-01-2 3-(4-chlorophenyl)-1,1,1-trifluorobut-3-en-2-ol 
• 89619-10-3 1-(1-bromovinyl)-4-chlorobenzene 
• 873-73-4 4-n-chlorophenylacetylene 

Downstream Products

• 89619-25-0 (E)-2-(4-chlorophenyl)-4,4,4-trifluorobut-2-en-1-yl 2,2,2-trifluoroethyl ether 
• 89619-26-1 (Z)-2-(4-chlorophenyl)-4,4,4-trifluorobut-2-en-1-yl 2,2,2-trifluoroethyl ether 
• 89619-32-9 (E)-2-(4-chlorophenyl)-4,4,4-trifluorobut-2-en-1-ol 
• 89618-97-3 (E)-2-(4-chlorophenyl)-4,4,4-trifluorobut-2-en-1-yl trifluoromethanesulfonate 

Relevant academic research and scientific papers

Effect of the α-Trifluoromethyl Moiety on the Solvolysis of Allylic Sulfonates

A series of allylic sulfonates bearing aryl substituents on the 2-position and/or trifluoromethyl groups on the 1- and/or 3-positions has been studied under solvolytic conditions in 2,2,2-trifluoroethanol.Nonarylated 1,3-di(trifluoromethyl)-substituted allylic sulfonates did not solvolyze in a conventional manner but instead gave products diagnostic of a complex isomerization-cleavage process.Mono(trifluoromethyl)-substituted allylic sulfonates solvolyzed by normal paths to give kH/kCF3 ratios of 2E6 and 4E4 for the substitution at the 1- and 3-positions, respectively.No evidence for 1,3-? interactions was discerned.