89619-10-3

Basic information

• Product Name: 1-(1-BROMOVINYL)-4-CHLOROBENZENE, 90%
• Synonyms: 1-(1-BroMovinyl)-4-chlorobenzene 90%
• CAS NO: 89619-10-3
• Molecular Formula: C₈H₆BrCl
• Molecular Weight: 217.49
• Product Categories: Alkenes;Aryl;Boronic Acids;Organic Building Blocks;AcyclicBoronic Acids and Derivatives
• Mol File: 89619-10-3.mol
• Article Data: 17

Chemical Properties

• Boiling Point: 263.1°C at 760 mmHg
• Flash Point: 110 °C
• Appearance: /
• Density: 1.539 g/mL at 25 °C
• Vapor Pressure: 0.0171mmHg at 25°C
• Refractive Index: n20/D 1.605
• CAS DataBase Reference: 1-(1-BROMOVINYL)-4-CHLOROBENZENE, 90%(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(1-BROMOVINYL)-4-CHLOROBENZENE, 90%(89619-10-3)
• EPA Substance Registry System: 1-(1-BROMOVINYL)-4-CHLOROBENZENE, 90%(89619-10-3)

Safety Data

• Hazard Codes: Xn,N
• Statements: 22-37/38-41-51/53
• Safety Statements: 26-36/37/39-61
• RIDADR: UN 3082 9/PG 3
• WGK Germany: 3
• Hazardous Substances Data: 89619-10-3(Hazardous Substances Data)

Usage

General Description

1-(1-Bromovinyl)-4-chlorobenzene, 90% is a chemical compound that is predominantly made up of 1-(1-Bromovinyl)-4-chlorobenzene. 1-(1-BROMOVINYL)-4-CHLOROBENZENE, 90% is 90% pure, indicating a high level of concentration. 1-(1-Bromovinyl)-4-chlorobenzene is a halogenated benzene derivative, with a bromine atom and a vinyl group attached to the benzene ring, as well as a chlorine substituent. It has applications in organic synthesis and can be used as a building block in the production of various other chemical compounds. This chemical is flammable and should be handled with care in a controlled laboratory environment.

InChI:InChI=1/C8H6BrCl/c1-6(9)7-2-4-8(10)5-3-7/h2-5H,1H2

Upstream product

• 873-73-4 4-n-chlorophenylacetylene 
• 23135-16-2 1,2-dibromo-1-(4-chlorophenyl)ethane 
• 1073-67-2 4-vinylbenzyl chloride 
• 75230-50-1 p-chloroacetophenone tosylhydrazone 
• 99-91-2 para-chloroacetophenone 
• 74-95-3 1,1-dibromomethane 
• 187409-10-5 3-chloro-α,β-dibromoethylbenzene 

Downstream Products

• 1579298-08-0 1-(1-(4-chlorophenyl)vinyl)cyclobutan-1-ol 
• 1579298-28-4 (S)-2-(chloromethyl)-2-(4-chlorophenyl)cyclopentanone 
• 1579298-17-1 3-(1-(4-chlorophenyl)vinyl)oxetan-3-ol 
• 536-38-9 4-chlorobenzoylmethyl bromide 
• 53503-49-4 ethyl 4-(4-chlorophenyl)-4-oxobutanoate 

Relevant articles and documents

Absence of Intermediates in the BINOL-Derived Mg(II)/Phosphate-Catalyzed Desymmetrizative Ring Expansion of 1-Vinylcyclobutanols

The catalyzed desymmetrizative ring expansion of alkenylcyclobutanols promoted by halofunctionalization of the alkene moiety with N-bromosuccinimide has been experimentally and computationally studied. The reaction yields highly enantioenriched cyclopenta

Catalytic Asymmetric Halogenation/Semipinacol Rearrangement of 3-Hydroxyl-3-vinyl Oxindoles: A Stereodivergent Kinetic Resolution Process

A highly enantioselective halogenation/semipinacol rearrangement of isatin-derived allylic alcohols has been developed with a chiral N,N′-dioxide/ScIII complex as catalyst. This strategy involved a pivotal stereodivergent kinetic resolution process and provided a facile and efficient entry to optically active halo-substituted quinolone derivatives and quinoline alkaloids with a quaternary stereocenter simultaneously under mild reaction conditions. Based on the control experiments together with kinetic studies and DFT calculations, a possible catalytic cycle was proposed to illustrate the reaction process and enantiocontrol.

Electrochemical Semipinacol Rearrangements of Allylic Alcohols: Construction of All-Carbon Quaternary Stereocenters

The first examples of electrochemical trifluoromethylation and sulfonylation/semipinacol rearrangements of allylic alcohols were developed using cheap and stable RSO2Na (R = CF3, Ph) as reagents. Various β-trifluoromethyl and sulfonated ketones were obtained in moderate to excellent yields. This strategy provides a facile, direct, and complementary approach to construct all-carbon quaternary stereocenters. In addition, the reaction has the advantages of being chemical oxidant-free and metal-free and has safe and mild reaction conditions.