89619-30-7

Upstream product

• 104798-41-6 (4,4,4-trifluorobut-1-en-2-yl)benzene 
• 1380233-12-4 C₁₀H₉F₃O 
• 28143-79-5 1-phenyl vinyl triflate 
• 77130-15-5 2-phenylallyltrimethylsilane 
• 98-86-2 acetophenone 
• 89619-00-1 3-phenyl-1,1,1-trifluorobut-3-en-2-ol 
• 89618-89-3 3-phenyl-1,1,1-trifluorobut-3-en-2-yl trifluoromethanesulfonate 

Downstream Products

• 89618-96-2 (E)-2-phenyl-4,4,4-trifluorobut-2-en-1-yl trifluoromethanesulfonate 

Relevant academic research and scientific papers

Copper-catalyzed trifluoromethylation of allylsilanes

CF3 on Csp3: Trifluoromethylation of allylsilane derivatives was accomplished through the use of CuI and Togni's reagent (1) under mild conditions. The reaction of allylsilanes without a substituent in the 2-position gave vinylsilane derivative

Effect of the α-Trifluoromethyl Moiety on the Solvolysis of Allylic Sulfonates

A series of allylic sulfonates bearing aryl substituents on the 2-position and/or trifluoromethyl groups on the 1- and/or 3-positions has been studied under solvolytic conditions in 2,2,2-trifluoroethanol.Nonarylated 1,3-di(trifluoromethyl)-substituted allylic sulfonates did not solvolyze in a conventional manner but instead gave products diagnostic of a complex isomerization-cleavage process.Mono(trifluoromethyl)-substituted allylic sulfonates solvolyzed by normal paths to give kH/kCF3 ratios of 2E6 and 4E4 for the substitution at the 1- and 3-positions, respectively.No evidence for 1,3-? interactions was discerned.