89648-16-8Relevant academic research and scientific papers
Carbocyclic ring closure of unsaturated S-, Se-, and C-aryl glycosides
Sollogoub, Matthieu,Mallet, Jean-Maurice,Sinay, Pierre
, p. 362 - 364 (2000)
Triisobutylaluminum-promoted rearrangement of unsaturated glycosides containing electron-donating aglycons - such as C-aryl glycoside 1, or O-, S- , and Seglycosides - provides direct access to highly functionalized cyclohexane derivatives such as 2.
Triisobutylaluminium (TIBAL) promoted rearrangement of C-glycosides
Sollogoub, Matthieu,Sinay, Pierre
, p. 843 - 858 (2007/10/03)
Triisobutylaluminium-promoted rearrangement of unsaturated glycosides containing electron-donating aglycons, such as C-aryl glycosides, provides direct access to highly functionalised cyclohexane derivatives.
C-GLYCOSIDATION OF PYRIDYL THIOGLYCOSIDES
Williams, Robert M.,Stewart, Andrew O.
, p. 2715 - 2718 (2007/10/02)
The pyridylthioglycosides 1 are efficiently transformed into the corresponding C-glycosides via reaction with silver(I) triflate and a variety of carbon nucleophiles.
C-GLYCOSIDES FROM O-GLYCOSYL TRICHLOROACETIMIDATES
Schmidt, Richard R.,Hoffmann, Michael
, p. 409 - 412 (2007/10/02)
From O-glycosyl trichloroacetimidates 2, 9, and 13 and activated benzene derivatives C-aryl glycosides were obtained by mild Lewis acid catalysis.In most cases only one stereoisomer was formed, however, the α-alkoxyalkyl transfer took place not always by
